Lattice-gas modeling of CO adlayers on Pd(100)

Using a lattice-gas model with pairwise interactions, we study the ordered structures, coverage dependence of the heat of adsorption, and other experimentally observable behavior of adsorbed CO overlayers on Pd(100) single crystal surfaces. Transfer matrix and Monte Carlo methods give accurate information regarding the lattice-gas model that often contradicts simple mean-field-like analysis. We demonstrate the usefulness of the model by reproducing experimental results over a large range of pressures and temperatures.Comment: 6 pages, 5 figure

Spectral Efficiency Analysis of Multi-Cell Massive MIMO Systems with Ricean Fading

This paper investigates the spectral efficiency of multi-cell massive multiple-input multiple-output systems with Ricean fading that utilize the linear maximal-ratio combining detector. We firstly present closed-form expressions for the effective signal-to-interference-plus-noise ratio (SINR) with the least squares and minimum mean squared error (MMSE) estimation methods, respectively, which apply for any number of base-station antennas $M$ and any Ricean $K$-factor. Also, the obtained results can be particularized in Rayleigh fading conditions when the Ricean $K$-factor is equal to zero. In the following, novel exact asymptotic expressions of the effective SINR are derived in the high $M$ and high Ricean $K$-factor regimes. The corresponding analysis shows that pilot contamination is removed by the MMSE estimator when we consider both infinite $M$ and infinite Ricean $K$-factor, while the pilot contamination phenomenon persists for the rest of cases. All the theoretical results are verified via Monte-Carlo simulations.Comment: 15 pages, 2 figures, the tenth International Conference on Wireless Communications and Signal Processing (WCSP 2018), to appea

Symmetry-Breaking and Percolation Transitions in a Surface Reaction Model with Superlattice Ordering

A symmetry-breaking order-disorder transition of the Ising type is found in a nonequilibrium surface reaction model for CO oxidation incorporating superlattice ordering of adsorbed oxygen. We relate this transition to the percolation of superlattice domains of oxygen, and discuss the consequences for chemical diffusion of coadsorbed CO. The latter constitutes a new type of problem involving transport in disordered media